Avogadro's Number

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  1. Avogadro's Number Formula
  2. Avogadro's Number

Since Avogadro's number is 6.022 × 10 23, it only makes sense that the holiday starts at 6:02 a.m. Revelers tell chemistry jokes, blow bubbles of natural gas that they set ablaze, toast with drinks chilled by dry ice and even recite the mole pledge of allegiance. Avogadro’s number (also called “a mole”) is roughly 6.022×10^23. The number is precisely calculated so that when you have one mole of atoms of a given molecular weight M, it weighs M grams. The chemists are still with me, but they aren’t the ones asking the question. They determined “Avogadro’s number”, which is defined as the number of molecules contained in one mole of the substance. The Loschmidt constant is barely used, but Avogadro's number (6.022×10 23 ) finds wide application in physics and chemistry.

Avogadro

When the weather is nice, many people begin to work on their yards and homes. For many projects, sand is needed as a foundation for a walkway, or to add to other materials. Sand could be ordered by the pound, but that takes a lot of time to weigh out. The best bet is to order sand by the yard—meaning a cubic yard. The loader can easily scoop up what the buyer needs, and put it directly into their truck.

Avogadro's Number

It certainly is easy to count bananas or to count elephants (as long as you stay out of their way). However, you would be counting grains of sugar from your sugar canister for a long, long time. Atoms and molecules are extremely small—far, far smaller than grains of sugar. Counting atoms or molecules is not only unwise, it is absolutely impossible. One drop of water contains about (10^{22}) molecules of water. If you counted 10 molecules every second for 50 years, without stopping, you would have counted only (1.6 times 10^{10}) molecules. Put another way, at that counting rate, it would take you over 30 trillion years to count the water molecules in one tiny drop.

Chemists of the past needed a name that could stand for a very large number of items. Amadeo Avogadro (1776-1856), an Italian scientist, provided such a number. He is responsible for the counting unit of measure called the mole. A mole (left( text{mol} right)) is the amount of a substance that contains (6.02 times 10^{23}) representative particles of that substance. The mole is the SI unit for amount of a substance. Just like the dozen and the gross, it is a name that stands for a number. There are therefore (6.02 times 10^{23}) water molecules in a mole of water molecules. There also would be (6.02 times 10^{23}) bananas in a mole of bananas, if such a huge number of bananas ever existed.

Avogadro's Number Formula

The number (6.02 times 10^{23}) is called Avogadro's number, the number of representative particles in a mole. It is an experimentally determined number. A representative particle is the smallest unit in which a substance naturally exists. For the majority of elements, the representative particle is the atom. Iron, carbon, and helium consist of iron atoms, carbon atoms, and helium atoms, respectively. Seven elements exist in nature as diatomic molecules and they are (ce{H_2}), (ce{N_2}), (ce{O_2}), (ce{F_2}), (ce{Cl_2}), (ce{Br_2}), and (ce{I_2}). The representative particle for these elements is the molecule. Likewise, all molecular compounds such as (ce{H_2O}) and (ce{CO_2}) exist as molecules and so the molecule is their representative particle. For ionic compounds such as (ce{NaCl}) and (ce{Ca(NO_3)_2}), the representative particle is the formula unit. A mole of any substance contains Avogadro's number (left( 6.02 times 10^{23} right)) of representative particles.

Summary

  • A mole of any substance contains Avogadro's number (left( 6.02 times 10^{23} right)) of representative particles.

Contributors and Attributions

  • CK-12 Foundation by Sharon Bewick, Richard Parsons, Therese Forsythe, Shonna Robinson, and Jean Dupon.

Learning Objectives

  • Use Avogadro's number to convert to moles and vice versa given the number of particles of an element.
  • Know the definition of the mole.
  • Determine the formula mass of an ionic or molecular compound.
  • Determine the percent composition of each element in a compound from the chemical formula.

When objects are very small, it is often inconvenient or inefficient, or even impossible to deal with the objects one at a time. For these reasons, we often deal with very small objects in groups, and have even invented names for various numbers of objects. The most common of these is 'dozen' which refers to 12 objects. We frequently buy objects in groups of 12, like doughnuts or pencils. Even smaller objects such as straight pins or staples are usually sold in boxes of 144, or a dozen dozen. A group of 144 is called a 'gross'.

This problem of dealing with things that are too small to operate with as single items also occurs in chemistry. Atoms and molecules are too small to see, let alone to count or measure. Chemists needed to select a group of atoms or molecules that would be convenient to operate with.

Avogadro's Number:Counting Atoms

Owing to their tiny size, atoms and molecules cannot be counted by direct observation. But much as we do when 'counting' beans in a jar, we can estimate the number of particles in a sample of an element or compound if we have some idea of the volume occupied by each particle and the volume of the container. Once this has been done, we know the number of formula units (to use the most general term for any combination of atoms we wish to define) in any arbitrary weight of the substance. The number will of course depend both on the formula of the substance and on the weight of the sample. However, if we consider a weight of substance that is the same as its formula (molecular) weight expressed in grams, we have only one number to know: Avogadro's number.

Avogadro's number

Avogadro's number is known to ten significant digits:

[N_A = 6.022141527 times 10^{23}.]

However, you only need to know it to three significant figures:

[N_A approx 6.02 times 10^{23}. label{3.2.1}]

So (6.02 times 10^{23}) of what? Well, of anything you like: apples, stars in the sky, burritos. However, the only practical use for (N_A) is to have a more convenient way of expressing the huge numbers of the tiny particles such as atoms or molecules that we deal with in chemistry. Avogadro's number is a collective number, just like a dozen. Students can think of (6.02 times 10^{23}) as the 'chemist's dozen'.

Before getting into the use of Avogadro's number in problems, take a moment to convince yourself of the reasoning embodied in the following examples.

Things to understand about Avogadro's number

  • It is a number, just as is 'dozen', and thus is dimensionless.
  • It is a huge number, far greater in magnitude than we can visualize
  • Its practical use is limited to counting tiny things like atoms, molecules, 'formula units', electrons, or photons.
  • The value of NA can be known only to the precision that the number of atoms in a measurable weight of a substance can be estimated. Because large numbers of atoms cannot be counted directly, a variety of ingenious indirect measurements have been made involving such things as Brownian motion and X-ray scattering.

The Mole: 'A Dozen Eggs and a Mole of Sugar, Please'

The mole (symbol: mol) is the base unit of amount of substance ('number of substance') in the International System of Units or System International (SI), defined as exactly 6.02214076×1023 particles, e.g., atoms, molecules, ions or electrons. The current definition was adopted in November 2018, revising its old definition based on the number of atoms in 12 grams of carbon-12 (12C) (the isotope of carbon with relative atomic mass 12 Daltons by definition).

It is not obvious why eggs come in dozens rather than 10s or 14s, or why a ream of paper contains 500 sheets rather than 400 or 600. The definition of a mole—that is, the decision to base it on 12 g of carbon-12—is also arbitrary. The important point is that 1 mole of carbon—or of anything else, whether atoms, compact discs, or houses—always has the same number of objects: 6.02 × 1023.

The Mole

Video (PageIndex{1}) How big is a mole?

Converting Between Number of Atoms to Moles and Vice Versa

We can use Avogadro's number as a conversion factor, or ratio, in dimensional analysis problems. If we are given the number of atoms of an element X, we can convert it into moles of by using the relationship

[text{1 mol X} = 6.022 times 10^{23} text{ X atoms}.]

An example on the use of Avogadro's number as a conversion factor is given below for carbon.

Example (PageIndex{1}): Moles of Carbon

The element carbon exists in two primary forms: graphite and diamond. How many moles of carbon atoms is (4.72 times 10^{24}) atoms of carbon?

Solution

Steps for Problem SolvingThe element carbon exists in two primary forms: graphite and diamond. How many moles of carbon atoms is (4.72 times 10^{24}) atoms of carbon?
Identify the 'given'information and what the problem is asking you to 'find.'Given: (4.72 times 10^{24}) C atoms
Find: mol C
List other known quantities(1, mol = 6.022 times 10^{23}) C atoms

Prepare a concept map and use the proper conversion factor.

Cancel units and calculate.[4.72 times 10^{24} : cancel{text{C} : ce{atoms}} times frac{1 : text{mol} : ce{C}}{6.02 times 10^{23} : cancel{text{C} : ce{atoms}}} = 7.84 : text{mol} : ce{C} nonumber]
Think about your result.

The given number of carbon atoms was greater than Avogadro's number,so the number of moles of (ce{C}) atoms is greater than 1 mole. Since Avogadro's number is a measured quantity with three significant figures, the result of the calculation is rounded to three significant figures

Formula Mass

One skill needed in future chapters is the ability to determine the mass of the formula of various chemical substances. This quantity is called the formula mass. The formula mass is obtained by adding the masses of each individual atom in the formula of the substance. Because a proper formula is electrically neutral (with no net electrons gained or lost), the ions can be considered atoms for the purpose of calculating the formula mass.

Let us start by calculating the formula mass of sodium chloride (NaCl). This formula mass is the sum of the atomic masses of one sodium atom and one chlorine atom, which we find from the periodic table; here, we use the masses to two decimal places:

To two decimal places, the formula mass of NaCl is 58.44 amu.

For covalent substances, the formula represents the numbers and types of atoms composing a single molecule of the substance; therefore, the formula mass may be correctly referred to as a molecular mass. Consider chloroform (CHCl3), a covalent compound once used as a surgical anesthetic and now primarily used in the production of tetrafluoroethylene, the building block for the “anti-stick” polymer, Teflon. The molecular formula of chloroform indicates that a single molecule contains one carbon atom, one hydrogen atom, and three chlorine atoms. The average molecular mass of a chloroform molecule is therefore equal to the sum of the average atomic masses of these atoms.

For ionic compounds with polyatomic ions, the sum must include the number and mass of each atom in the formula for the polyatomic ion. as shown in the example below for aluminum sulfate, Al2(SO4)3.

Example (PageIndex{2}) Formula Mass for an Ionic Compound

Avogadro's Number

Aluminum sulfate, Al2(SO4)3, is an ionic compound that is used in the manufacture of paper and in various water purification processes. What is the formula mass (amu) of this compound?

Solution

The formula for this compound indicates it contains Al3+ and SO42− ions combined in a 2:3 ratio. For purposes of computing a formula mass, it is helpful to rewrite the formula in the simpler format, Al2S3O12. Following the approach outlined above, the formula mass for this compound is calculated as follows:

The formula mass for Al2(SO4)3, is 342.14 amu.

Exercise (PageIndex{1})

Use the atomic masses (rounded to two decimal places) to determine the formula mass for each ionic compound.

  1. TiO2
  2. AgBr
  3. Au(NO3)3
  4. Fe3(PO4)2

Answer

a. 79.87 amu

b. 187.77 amu

c. 383.0 amu

Percent Composition of a Compound from a Chemical Formula

The percent composition of a compound can also be determined from the formula of the compound. The subscripts in the formula are first used to calculate the mass of each element in one mole of the compound. That is divided by the molar mass of the compound and multiplied by (100%).

[% : text{by mass} = frac{text{mass of element in} : 1 : text{mol}}{text{molar mass of compound}} times 100%]

The percent composition of a given compound is always the same as long as the compound is pure.

Example (PageIndex{3})

Dichlorine heptoxide (left( ce{Cl_2O_7} right)) is a highly reactive compound used in some organic synthesis reactions. Calculate the percent composition of dichlorine heptoxide.

Solution

Steps for Problem SolvingCalculate the percent composition of dichlorine heptoxide (left( ce{Cl_2O_7} right)).
Identify the 'given'information and what the problem is asking you to 'find.'

Given : Cl2O7

Find: % Composition (% Cl and %O)

List other known quantities

Mass of Cl in 1 mol Cl2O7 , 2 Cl : 2 x 35.45 g = 70.90 g

Mass of O in 1 mol Cl2O7 , 7 O: 7 x 16.00 g = 112.00 g

Molar mass of Cl2O7 = 182.90 g/mol

Cancel units and calculate.

[% ce{Cl} = frac{70.90 : text{g} : ce{Cl}}{182.90 : text{g}} times 100% = 38.76% : ce{Cl} nonumber]

[% : ce{O} = frac{112.00 : text{g} : ce{O}}{182.90 : text{g}} times 100% = 61.24% : ce{O} nonumber]

Calculate the percent by mass of each element by dividing the mass of that element in 1 mole of the compound by the molar mass of the compound and multiplying by (100%).

Think about your result.The percentages add up to (100%).

Percent composition can also be used to determine the mass of a certain element that is contained in any mass of a compound. In the previous sample problem, it was found that the percent composition of dichlorine heptoxide is (38.76% : ce{Cl}) and (61.24% : ce{O}). Suppose that you needed to know the masses of chlorine and oxygen present in a (12.50 : text{g}) sample of dichlorine heptoxide. You can set up a conversion factor based on the percent by mass of each element.

Avogadro

[12.50 : text{g} : ce{Cl_2O_7} times frac{38.76 : text{g} : ce{Cl}}{100 : text{g} : ce{Cl_2O_7}} = 4.845 : text{g} : ce{Cl}]

[12.50 : text{g} : ce{Cl_2O_7} times frac{61.24 : text{g} : ce{O}}{100 : text{g} : ce{Cl_2O_7}} = 7.655 : text{g} : ce{O}]

The sum of the two masses is (12.50 : text{g}), the mass of the sample size.

Exercise (PageIndex{2})

Barium fluoride is a transparent crystal that can be found in nature as the mineral frankdicksonite. Determine the percent composition of barium fluoride.

Answer a:
78.32% Ba and 21.67% F

Summary

  • The mole (symbol: mol) is the base unit of amount of substance ('number of substance') in the International System of Units or System International (SI), defined as exactly 6.02214076×1023 particles, e.g., atoms, molecules, ions or electrons.
  • Avogadro's number is related to moles of any substance X as follows:

[text{1 mol X} = 6.022 times 10^{23} text{ X atoms}.]

  • Formula masses of ionic and molecular compounds can be determined from the masses of the atoms in their formulas.
  • Processes are described for calculating the percent composition of a compound based on the chemical formula.
  • Anonymous

  • Paul Flowers (University of North Carolina - Pembroke), Klaus Theopold (University of Delaware) and Richard Langley (Stephen F. Austin State University) with contributing authors. Textbook content produced by OpenStax College is licensed under a Creative Commons Attribution License 4.0 license. Download for free at http://cnx.org/contents/[email protected]).

  • Stephen Lower, Professor Emeritus (Simon Fraser U.) Chem1 Virtual Textbook

  • Marisa Alviar-Agnew (Sacramento City College)

  • Henry Agnew (UC Davis)

  • Wikipedia